Parr-instrument 6400 Instrukcja Użytkownika

587M6400Automatic Isoperibol CalorimeterOperating Instruction ManualFor models produced after October 2010

1InstallationParr Instrument Company8chaPter 1InstallationNote: Some of the following manual sections contain information in the form of warnings, cau

14DrawingsParr Instrument Company98Figure 14-18A1450DD Bomb Head Assembly, View 2

Drawings640014www.parrinst.com99Figure 14-19A1050DD Rinse Collection AssemblyCHECKEDBYBYSCALEPART NO.DATEDRAWNUNLESS OTHERWISE SPECIFIEDDESCRIPTIONREV

14DrawingsParr Instrument Company100Figure 14-20Wiring Diagram

Drawings640014www.parrinst.com101Figure 14-21Wiring Diagram

14DrawingsParr Instrument Company102Figure 14-22Fuse Diagram

www.parrinst.com103Notes 640014

15TablesParr Instrument Company104chaPter 15 TablesTable 15-1Factory Default SettingsCalorimeter OperationsOperating Mode DeterminationBomb Installed/

Tables640015www.parrinst.com105DeterminationFixed Fuse Correction ON 50.0Acid Correction Fixed HN03 8.0Fixed Sulfur Correction OFF 0.0Net Heat/Dry Fa

15TablesParr Instrument Company106Table 15-2Settings for ISO & BSI MethodsPage Line Setting ValueThermochemical CorrectionsAcid Correction (STD) E

Installation64001www.parrinst.com9The type of tubing and the wall thickness also has an effect on the amount of tightening required. Plastic tubing re

587M R03 02/11/14

1InstallationParr Instrument Company10Figure 1-26400 Calorimeter Back Panel

Installation64001www.parrinst.com11Water ConnectionRemove the cap plug on the water filling elbow and fill the internal reservoir tank with water having

1InstallationParr Instrument Company12Gas ConnectionMake the connections to the oxygen supply at this time. Refer to Figure 1-3. 1/8” O.D. nylon pre

Installation64001www.parrinst.com13Mettler 011/012 InterfaceThe ID field must contain “S_” to indicate a stable mass. The data field con-tains the curr

1InstallationParr Instrument Company14Figure 1-46400 Calorimeter PeripheralsFigure 1-5Multiple Alternate Configurations

www.parrinst.com15Notes 64001

2Quick StartParr Instrument Company16chaPter 2Quick StartInitial FillWhen you first fill the calorimeter with water the main reservoir will be filled. Th

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3OperationParr Instrument Company18chaPter 3OperationMenu SystemAll configurations and operations are handled by a menu-driven system operated from the

Operation64003www.parrinst.com19ProgrammingThe program in the 6400 Calorimeter can be exten-sively modified to tailor the unit to a wide variety of ope

3OperationParr Instrument Company20combustions. If moisture is to be added to retard the combustion rate, drop the water directly onto the loose samp

Operation64003www.parrinst.com21Volatile Sample HoldersVolatile samples are defined as one with an initial boiling point below 180 ºC. Volatile sample

3OperationParr Instrument Company22Combustion CapsulesNon-volatile samples to be tested in Parr oxygen bombs are weighed and burned in shallow capsule

Operation64003www.parrinst.com23Fill CycleOnce the calorimeter is started and the cover is closed, the fill sequence begins.Figure 3-3Bucket Fill Flow

3OperationParr Instrument Company24Pre-PeriodAt the completion of the fill sequence, the pre-period begins.Figure 3-4Pre-Period/Post-Period Flow Diagra

Operation64003www.parrinst.com25Bomb FiringOnce the initial equilibrium is confirmed, the con-troller initiates the firing sequence. There are no chang

3OperationParr Instrument Company26Cool/RinseAt the completion of the post-period, the rinse and cool sequence begins.Figure 3-5Rinse & Cool Flow

Operation64003www.parrinst.com27DrainAt the completion of the bomb rinse sequence, the drain sequence begins.Figure 3-6Drain Flow Diagram The water in

www.parrinst.comTable of Contents64001Preface 4Scope 4Related Instructions 4Purpose 4Explanation of Symbols 5Safety Information 5Intended Usage

4Menu DescriptionsParr Instrument Company28chaPter 4Menu DescriptionsNote: Keys which make global changes to the setup of the calorimeter contain a Y

Menu Descriptions64004www.parrinst.com29Temperature vs. Time PlotSetup: Press the Setup key to access the Tem-perature Plot Setup Menu, which has man

4Menu DescriptionsParr Instrument Company30Operating Controls MenuMethod of Operation: Offers an operating mode of either dynamic or equilibrium. In

Menu Descriptions64004www.parrinst.com31Bomb Rinse Tank ControlsReport Rinse Tank Empty: When turned on the calorimeter will notify the user when it

4Menu DescriptionsParr Instrument Company32Program Information and Control MenuDate & Time: Accesses a sub-menu to set the cur-rent date and ti

Menu Descriptions64004www.parrinst.com33User/Factory Settings: This key leads to a sub-menu that allows the user to save or recall user defined instru

4Menu DescriptionsParr Instrument Company34Calibration Data and Controls MenuCalibration Run Limit: Displays the maximum number of runs that will be

Menu Descriptions64004www.parrinst.com35Bomb 1The following four values are displayed for the Bomb # shown in the title on top of the screen. » Bomb E

4Menu DescriptionsParr Instrument Company36Thermochemical Corrections MenuThe Thermochemical Corrections Menu permits three types of fixed corrections

Menu Descriptions64004www.parrinst.com37Calculation Factors: Accesses the Calculation Fac-tors sub-menu, which provides for setting a number of optio

Parr Instrument CompanyTable of Contents2Chapter 5 46Reports 46Reports 46Chapter 6 48Standardizations 48Standardizing the Calorimeter 48Standard

4Menu DescriptionsParr Instrument Company38Net Heat/Dry Factors: Accesses the Net Heat/Dry Factors sub-menu, which provides for setting the net heat

Menu Descriptions64004www.parrinst.com39Hydrogen Entry Mode: This key steps through the options for entering hydrogen content for calculating the net

4Menu DescriptionsParr Instrument Company40Moisture as Determined (MAD) Entry Mode: This key steps through the options for entering the moisture as d

Menu Descriptions64004www.parrinst.com41Communication Controls MenuAccesses sub-menus which set the communications protocols for the printer and balan

4Menu DescriptionsParr Instrument Company42 » Transfer Timeout (seconds). This value determines how long the interface will wait before giving up on

Menu Descriptions64004www.parrinst.com43Run Data File ManagerThe white upper portion of the Run Data File Manag-er screen presents all tests in memory

4Menu DescriptionsParr Instrument Company44Data Logger ControlsData Logger: This key toggles the data logging function ON/OFF.Data Log Interval: Thi

Menu Descriptions64004www.parrinst.com45User Defined ButtonsCombine Det. Reports: Pressing this key com-bines all determination reports into a single

5ReportsParr Instrument Company46chaPter 5ReportsReportsThe 6400 Calorimeter can transmit its stored test data in either of two ways. The AUTO REPORT

www.parrinst.com47Notes 64005

www.parrinst.comTable of Contents64003Figures Figure 1-1Swagelok Tube Fittings 8Figure 1-26400 Calorimeter Back Panel 10Figure

6StandardizationsParr Instrument Company48chaPter 6StandardizationsStandardizing the CalorimeterThe Energy Equivalent FactorThe term “standardization”

Standardizations64006www.parrinst.com49Any outliers or other tests which should not be included in the average EE Value must be deleted from the memor

6StandardizationsParr Instrument Company50Table 6-2Calorimeter Control Limit Values in cal/g When Benzoic Acid is Used as a Test SampleAccepted heat o

Standardizations64006www.parrinst.com51Table 6-3Calorimeter Control Limit Values in BTU/lb When Benzoic Acid is Used as a Test SampleAccepted heat of

7CalculationsParr Instrument Company52chaPter 7CalculationsCalculating the Heat of CombustionThe 6400 Calorimeter will automatically make all of the c

Calculations64007www.parrinst.com53Users may find it convenient to enter a fixed value for the fuse correction and avoid the need to de-termine this cor

7CalculationsParr Instrument Company54Thermochemical Calculation DetailsTraditionally, standard solutions and procedures have been established to simp

Calculations64007www.parrinst.com55Using the default acid and sulfur multipliers as well as a heat of formation of nitric acid of 14.1 cal/milliequiv-

7CalculationsParr Instrument Company56ASTM Treatment for Acid and SulfurIn the ASTM treatment, the correction for acid formation assumes that all the

Calculations64007www.parrinst.com57Spiking SamplesIt is sometimes necessary to add a spiking material to samples which are very small, have a low heat

PrefaceParr Instrument Company4Preface ScopeThis manual contains instructions for installing and operating the Parr 6400 Calorimeter. For ease of use

8Computer CommunicationsParr Instrument Company58chaPter 8Computer CommunicationsComputer ConnectionsIf the 6400 Calorimeter is to be connected to a c

Computer Communications64008www.parrinst.com59Samba Server Feature (Optional)Samba was originally developed as an implementa-tion of the SMB (Server M

8Computer CommunicationsParr Instrument Company60The calorimeter offers a web server service. Test reports can be viewed with a web browser using a UR

Computer Communications64008www.parrinst.com61Clicking on the Config button will display the screen below. Changes made on this screen will change the

8Computer CommunicationsParr Instrument Company62Clicking on the Run Data button displays a list of reports currently in the instrument memory.Clickin

Computer Communications64008www.parrinst.com63Clicking on the System Info button will display the screen below.

8Computer CommunicationsParr Instrument Company64Clicking on the LCD Snap Shot button will display the current menu screen displayed by the calorimete

Computer Communications64008www.parrinst.com65Clicking on the Documentation button will display the screen below. Clicking on any of the links will op

8Computer CommunicationsParr Instrument Company66Bar Code PortThe use of barcodes in the laboratory has become a highly accurate, rapid and inexpensiv

Computer Communications64008www.parrinst.com67Table 8-26400 Calorimeter Run Data TemplateField DescriptionSampleID char[16]Timestamp MM/DD/YY HH:mm:ss

Preface6400www.parrinst.com5Safety InformationTo avoid electrical shock, always:1. Use a properly grounded electrical outlet of correct voltage and c

9Memory ManagementParr Instrument Company68chaPter 9 Memory Management The 6400 Calorimeter will hold data for 1000 tests in its memory. These tests

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10MaintenanceParr Instrument Company70chaPter 10 Maintenance Note: Some of the following manual sections contain information in the form of warning

Maintenance640010www.parrinst.com71FusesThe replacement of protective fuses for the 6400 Calorimeter should be performed by qualified personnel. All fu

10MaintenanceParr Instrument Company72The 1140DD Seal/Release mechanism should be ser-viced with the same frequency as the bomb head. This includes t

Maintenance640010www.parrinst.com736400 Maintenance ChecklistQuarterly MaintenanceDate Date Date Date1. Change water2. Replace 149C3. Clean grill o

11TroubleshootingParr Instrument Company74chaPter 11Troubleshooting Bomb Exhaust TroubleshootingThe bomb exhaust and sealing is controlled by movemen

Troubleshooting640011www.parrinst.com75The third condition can be eliminated by following the procedure outlined in the section servicing the O-rings

11TroubleshootingParr Instrument Company76Error ListThe calorimeter will run a number of diagnostic checks upon itself and will advise the operator if

Troubleshooting640011www.parrinst.com77Bomb ID – Has Been Fired – Times Which Exceeds the Bomb Service Interval.The calorimeter controller keeps track

PrefaceParr Instrument Company6General SpecificationsElectrical Ratings120VAC, 5.0 Amps. 50/60 Hz240VAC, 3.0 Amps. 50/60 HzBefore connecting the calori

12Technical ServiceParr Instrument Company78chaPter 12Technical Service Should you need assistance in the operation or service of your instrument, ple

www.parrinst.com79Notes 640012

13Parts ListsParr Instrument Company80chaPter 13Parts ListsPrincipal Assemblies in CalorimeterItem Description1138/1138CL Oxygen Combustion Vessel1795

Parts Lists640013www.parrinst.com81A1255DD Bucket Stirrer AssemblyItem Description682DD Snap Ring, Internal .50683DD Wave Spring, .50 OD684DD Ball Bea

14DrawingsParr Instrument Company82chaPter 14 DrawingsFigure 14-11138 Parts Diagram

Drawings640014www.parrinst.com831138 Parts Diagram KeyKey Item Description1 888DD2 Cylinder2 889DD Outer Ring3 821DD O-ring 1/16 ID NBR4 668DD Check V

14DrawingsParr Instrument Company84Figure 14-26400 Cutaway Right

Drawings640014www.parrinst.com85Figure 14-36400 Cutaway Left

14DrawingsParr Instrument Company86Figure 14-46400 Cover Open1324DD2LockingPost

Drawings640014www.parrinst.com87Figure 14-5A1250DD2 Control SchematicP8USB PORTJ8J10P6J1A1821EPIN #1USB PORTJ5J1BOARD TODISPLAY CABLEIO BOARDA2163E LC

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14DrawingsParr Instrument Company88Figure 14-6A1251DD Oxygen Solenoid AssemblyFigure 14-7A1447DD Water Solenoid Assembly

Drawings640014www.parrinst.com89Figure 14-8A1456DD Rinse Valve Assembly

14DrawingsParr Instrument Company90Figure 14-96400 Internal Plumbing Diagram

Drawings640014www.parrinst.com91Figure 14-106400 Water Tank and Jacket Cooling Solenoid

14DrawingsParr Instrument Company92Figure 14-11A1455DD Propeller AssemblyApply thread sealant (Locktite or equivalent to set screw in 1242DD2 pulley b

Drawings640014www.parrinst.com93Figure 14-13A1268DD Stirrer Motor and Mount

14DrawingsParr Instrument Company94Figure 14-146400 Bucket Assembly

Drawings640014www.parrinst.com95Figure 14-156400 Air Can Assembly, Cutaway Left

14DrawingsParr Instrument Company96Figure 14-166400 Air Can Assembly, Cutaway Front

Drawings640014www.parrinst.com97Figure 14-17A1450DD Bomb Head Assembly, View 1